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钩吻(Gelsemium elegans)生物碱结构类型增补探讨
张 振1, 杨小生2, 邸迎彤3, 何红平3, 郝小江3*
1.贵州大学 化学与化工学院, 贵阳 550025;2.贵州省、中国科学院天然产物化学重点实验室, 贵阳 550002;3.中国科学院 昆明植物研究所, 昆明 650204
摘要:
根据对亚洲钩吻(Gelsemium elegans)的化学研究结果,探讨将已知5种生物碱骨架类型扩展为9种,其中新增补并命名为Geleboline-type,Gelselegine-type,Gelsemamide-type,以及首次报道在亚洲钩吻中得到的Yohimbane-type类型。
关键词:  钩吻  生物碱类型  骨架
DOI:10.3969/j.issn.1000-3142.2013.02.001
分类号:R932
Fund project:
Investigation on the additional alkaloid-types on Gelsemium elegans
ZHANG Zhen1, YANG Xiao-Sheng2, DI Ying-Tong3, HE Hong-Ping3, HAO Xiao-Jiang3*
1.College of Chemical Engineering, Guizhou University, Guiyang 550001, China;2.Key Laboratory of Chemistry for Natural Products of Guizhou Province and Chinese Academy of Sciences, Guiyang 550002, China;3.Kunming Institute of Batany, Chinese Academy of Sciences, Kunming 650204, China
Abstract:
According to a series of the results of the chemical research on Gelsemium elegans,the alkaloid-types were added from five to nine types,including three additional types that named as Geleboline-type,Gelselegine-type,Gelsemamide-type,and Yohimbane-type that was reported at the first time on G.elegans.
Key words:  Gelsemium elegans  alkaloid-type  skeleton
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