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木奶果茎叶的化学成分研究
宁德生, 吴云飞, 吕仕洪, 潘争红
1. 广西植物功能物质研究与利用重点实验室, 广西植物研究所, 广西 桂林 541006;2. 云南师范大学, 昆明 650500
摘要:
采用常压柱色谱和重结晶相结合的分离方法,从木奶果的茎叶提取物的乙酸乙酯部分中分离得到8个化合物,通过波谱方法及与已知样品对照的手段鉴定它们为(2S,3S,4R)-2-[(2R)-2-hydroxytetracosanoylamino]-1,3,4-octadecanetriol(1),Aralia cerebroside(2),(24S)-24-ethylcholesta-3β,5α,6β-triol(3),Stigmast-4-en-6β-ol-3-one(4),7-oxo-β-sitosterol(5),7α-methoxy-sigmast-5-en-3β-ol(6),β-sitosterol(7),daucosterol(8)。化合物1-6为首次从该种植物中发现的。
关键词:  木奶果  甾醇  化学成分
DOI:10.3969/j.issn.1000-3142.2014.02.005
分类号:Q946.8
Fund project:
Chemical constituents of the stem and leaves of Baccaurea ramiflora
NING De-Sheng1, WU Yun-Fei1, LÜ Shi-Hong1, PAN Zheng-Hong1*
1. Guangxi Key Laboratory of Functional Phytochemicals Research and Utilization, Guangxi Institute of Botany, Guilin 541006, China;2. Yunnan Normal University, Kunming 650500, China
Abstract:
Eight compounds were isolated from the stems and leaves of Baccaurea ramiflora by separation method of the normal pressure column chromatography and recrystallization. On the basis of spectral data or comparison with authentic samples,they were identified as(2S,3S,4R)-2-[(2R)-2-hydroxytetracosanoylamino]-1,3,4-octadecanetriol(1),Aralia cerebroside(2),(24S)-24-ethylcholesta-3β,5α,6β-triol(3),stigmast-4-en-6β-ol-3-one(4),7-oxo-β-sitosterol(5),7α-methoxy-sigmast-5-en-3β-ol(6),β-sitosterol(7),daucosterol(8). Compounds 1-6 were firstly isolated from this plant.
Key words:  Baccaurea ramiflora  steroids  chemical constituents
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